橡胶技术网

弹性体
CHINA ELASTOMERICS
2004 Vol.14 No.2 P.62-66

橡胶技术网

聚合物光接枝表面改性的方法和影响因素

The method and the effective factors of the surface photografting modification of polymers

秦立红  刘曲锋 

摘 要:简要介绍了聚合物光接枝表面改性的方法,并分析了聚合物光接枝表面改性的几种方法,着重分析了基体、接枝单体、光敏剂、溶剂、接枝方法、温度和光照时间等因素对聚合物光接枝表面改性的影响.
关键词:光接枝;表面改性;聚合物
分类号:TQ314.24+6  文献标识码:A

文章编号:1005-3174(2004)02-0062-05

作者简介:秦立红(1975-),女,山东潍坊人,学士学位,主要从事产品开发和产品检测工作,联系电话:0532-4851022-2383.
作者单位:秦立红(青岛海晶化工集团,山东,青岛,266042) 
     刘曲锋(山东工艺品进出口集团发制品厂,山东,青岛,266109) 

参考文献:

[1]Kubota H., Nagaoka N., Katakai R.. Temperature-responsive characteristics of n-isopropylacrylamide-grafted polymer films prepared by photografting[J]. J. Appl. Polym. Sci., 1994,51:925~929.
[2]Bai G., Hu X., Yan Q.. Surface modification of polyethylene film by liquid phase photograft polymerization[J]. Polym. Bull,1996,36:503~508.
[3]Edge S., Walker S., Feast W.J.. Surface modification of polyethylene by photochemical grafting with 2-hydroxyethymethacrylate[J]. J. Appl. Polym. Sci.,1993,47:1075~1082.
[4]Kutoba H., Shigehisa Y.. Introduction of amidoxime groups into cellulose and its ability to adsorb metal ions[J]. J. Appl. Polym. Sci., 1995,56:147~151.
[5]Ranby B., Gao Z.M., Hult A., Zhang P.Y., Modification of polymer surfaces by graft copolymerization[J]. ACS Polym. Prep. , 1986,27:38~39.
[6]Yang W., Ranby B.. Bulk surface photografting process and its applications. I. Reactions and kinetics[J]. J. Appl. Polym. Sci., 1996,62:533~543.
[7]Yang W., Ranby B.. Bulk surface photografting process and its applications. II. Principal factors affecting surface photografting[J].J. Appl. Polym. Sci., 1996,62:545~555.
[8]Wang T., Kang ET, Neoh KG, et al.Surface modification of low-density polyethylene films by UV-induced graft copolymerization and its relevance to photolamination[J].Langmuir, 1998,14(4):921~927.
[9]Kubota H., Nagaoka N., Katakai R.. Temperature-responsive characteristics of n-isopropylacrylamide-grafted polymer films prepared by photografting[J]. J. Appl. Polym. Sci., 1994,51:925~929.
[10]"Kubota H., Ogiwara Y.. Effect of water in vapor-phase photografting of vinyl monomers on polymer films[J]. J. Appl. Polym. Sci., 1991,43:1001~1005.
[11]"Ma HM, Davis RH, Bowman CN. Principal factors affecting sequential photoindeced graft polymerization[J].POLYMER,2001,42 (20):8333~8338.
[12]"Kubota H., Koike N., Ogiwara Y..Locationof methacrylic acid-grafted chains introduced into polyolefin films by means of photografting[J]. J. Appl. Polym. Sci.: Part C: Polym Lett Ed., 1987,25:273.
[13]"Yang W., Ranby B.. Bulk surface photografting process and its applications. I. Reactions and kinetics[J]. J. Appl. Polym. Sci., 1996,62:533~543.
[14]"K.Yamada, T.Kimura,H.Tsutaya. Hydrophilic and adhesive properties of methacrylic acid-grafted polyethylene plates[J].J. Appl. Polym. Sci., 1992,44:993~1001.
[15]"Kubota H.. Photografting of acrylonitrile and methacrylic acid on polyethylene film under air atmosphere[J]. J. Appl. Polym. Sci., 1993,48:1717~1721.


收稿日期:2003年11月10日

出版日期:2004年4月25日

请看PDF全文